Is Pokemon Diamond & Pearl: Clip Show hentai?
No
Rated PG (Children) on MyAnimeList and not tagged as Hentai.

TV Special · 2006 · 1 episodes · PG - Children
Action, Adventure, Comedy, Fantasy, Kids
A compilation of old clips from Satoshi's journeys. It was aired during the episode 1-3 special on Japanese TV, between episode 2 and 3. (Source: AniDB, edited)
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