Is Madan no Ou to Vanadis: Tigre-kun to Vanadi-chu Episode 0 hentai?
No
Rated G (All Ages) on MyAnimeList and not tagged as Hentai.

ONA · 2014 · 1 episodes · G - All Ages
Comedy, Parody
Episode 0 of Madan no Ou to Vanadis: Tigre-kun to Vanadi-chu.
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