Is Pokemon: Pikachu no Fushigi na Fushigi na Daibouken hentai?
English title: Pokémon: Pikachu's Big Mysterious Adventure
No
Rated PG (Children) on MyAnimeList and not tagged as Hentai.

Special · 2010 · 1 episodes · PG - Children
Adventure, Comedy, Fantasy, Kids
While being let out to play by their trainers, Pikachu and Piplup wind up separated from their Pokémon friends and wind up travelling with a Skitty into a strange dimension, unknowingly followed by Croagunk, Team Rocket's Pokémon and a Marill that's desperate to have someone hear her sing... (Source: Bulbapedia)
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