Is Shakugan no Shana S hentai?
English title: Shakugan no Shana S: OVA Series
No
Rated PG-13 (Teens 13 or older) on MyAnimeList and not tagged as Hentai.

OVA · 2009 · 4 episodes · PG-13 - Teens 13 or older
Action, Drama, Romance, School, Supernatural
Find out what happens when Yuji accidentally triggers a found Treasure Tool while it's pointed at Shana! Then, Yuji teams up with Wilhelmina to stalk their fiery friend—whose secrecy has become unsettling. Finally, in a two-part special, Shana tracks a Denizen's trail by sorting through a Torch's memories for clues. Her sleuth skills reveal a teenage girl's heartwarming last days and a predator with a serious identity crisis! (Source: FUNimation)
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